The TNSNames.ora Editor plug-in isn't referencing the TNS_ADMIN system environment variable. Instead, it's locating the tnsnames.ora file located in the \network\admin directory.
On my machine, TNS_ADMIN points to c:\oracle\admin. The plug-in isn't using the tnsnames.ora file in this location, although both Oracle and PL/SQL Developer do. Instead, it's using the tnsnames.ora file located in C:\oracle\product\10.2.0\client_1\NETWORK\ADMIN.