Well, I tried only on the first logon. Now, that you mentioned then I checked on the Tools > define connections and it is empty too.
So, in this case both are empty.
This is the logon screen I was talking about:
1. click on the PSD icon to start the program.
2. The PSD splash screen shows for a milisecond
3. the Logon windows gets in top of the PSD splash screen.
4. Entered my user (apps) and password.
5. The database field contains my last instance that I used the day before.
6. I click on the List of Values to search for other instances,but there is nothing. It is just blank.
7. If I entered any other instance name from my tnsnames, it works, the connection is successful. The list remains blank.
Same on the tools define connections the list is empty.
This was different during the beta test, the list was populated and all the instances from my tnsnames did show.