Hi Sanjay,
when you entered your SQL (in SQL-Window) you can Press F5 (Tools/Explain Plan), and there is a Drop-Down List where you can choose the optimizer Goal.
In SQL you can do this with hints. But if youre Oracle Version is higher then 9 i wouldn't use this. Oracle hints are depricated since 10g in my opinion. Cause the internal optimizers works in other ways then before.
Benjamin